(34)--13-3-1 片呐醇重排基础有机化学

PinacolPinacol重排重排CH3CCCH3H3CCH3OHOHH+PinanolCH3CCH3CCH3CH3O+H2OPinacoloneR2CCR4R1R3OHOHH+CCR1R4OR3+H2OR2作为催化剂的酸可以是作为催化剂的酸可以是无机酸无机酸或或有机酸有机酸，常用的有硫酸、盐酸、，常用的有硫酸、盐酸、磷酸、碘乙酸、乙酰氯、无水氯化锌磷酸、碘乙酸、乙酰氯、无水氯化锌--乙酐等乙酐等CH3CCCH3H3CCH3OHOHH+PinacolPinacol重排机理：重排机理：CH3CCCH3H3CCH3OHOH2CH3CCCH3H3CCH3OHH2OCH...